Metal cation assisted protonation of retinylidene Schiff base in aqueous acetonitrile and in reverse micelles

SINGH, AK; DAS, J

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dc.contributor.author	SINGH, AK	en_US
dc.contributor.author	DAS, J	en_US
dc.date.accessioned	2011-08-28T13:15:28Z	en_US
dc.date.accessioned	2011-12-26T12:58:03Z	en_US
dc.date.accessioned	2011-12-27T05:47:04Z
dc.date.available	2011-08-28T13:15:28Z	en_US
dc.date.available	2011-12-26T12:58:03Z	en_US
dc.date.available	2011-12-27T05:47:04Z
dc.date.issued	1996	en_US
dc.identifier.citation	JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, (8), 1739-1742	en_US
dc.identifier.issn	0300-9580	en_US
dc.identifier.uri	http://dx.doi.org/10.1039/p29960001739	en_US
dc.identifier.uri	http://dspace.library.iitb.ac.in/xmlui/handle/10054/11748	en_US
dc.identifier.uri	http://hdl.handle.net/10054/11748
dc.description.abstract	Metal cations (Ca2+, Mg2+, Zn2+) cause water to protonate all-trans-N-retinylidenebutylamine when solubilised in (i) acetonitrile containing aqueous MgBr2 and (ii) CaA(2), MgA(2) and ZnA(2) [where A = bis(2-ethylhexyl) sulfosuccinate anion] solubilised water pools in heptane. The results are discussed in terms of the role of metal cations and water in wavelength regulation in the opsin family of proteins.	en_US
dc.language.iso	en	en_US
dc.publisher	ROYAL SOC CHEMISTRY	en_US
dc.subject	Nuclear Magnetic-Resonance	en_US
dc.subject	Solubilized Water Pools	en_US
dc.subject	Purple Membrane	en_US
dc.subject	Bacteriorhodopsin	en_US
dc.subject	Rhodopsin	en_US
dc.subject	Molecule	en_US
dc.subject	Spectroscopy	en_US
dc.subject	Residues	en_US
dc.subject	Heptane	en_US
dc.subject	Model	en_US
dc.title	Metal cation assisted protonation of retinylidene Schiff base in aqueous acetonitrile and in reverse micelles	en_US
dc.type	Article	en_US