| dc.contributor.author |
PANDA K.N. |
|
| dc.contributor.author |
SENGUPTA R. |
|
| dc.contributor.author |
KUMAR A. |
|
| dc.contributor.author |
RAVIKANTH M. |
|
| dc.date.accessioned |
2023-03-17T04:52:41Z |
|
| dc.date.available |
2023-03-17T04:52:41Z |
|
| dc.date.issued |
2021 |
|
| dc.identifier.citation |
Journal of Organic Chemistry,86(5)3778-3784 |
en_US |
| dc.identifier.issn |
223263 |
|
| dc.identifier.uri |
https://dx.doi.org/10.1021/acs.joc.0c02585 |
|
| dc.identifier.uri |
http://localhost:8080/xmlui/handle/100/39318 |
|
| dc.description.abstract |
The aromatic 14πmeso-tetraaryl triphyrin(2.1.1)s were switched to stable antiaromatic 16πp(v) complexes of triphyrin(2.1.1) by refluxing free base triphyrin(2.1.1)s with pcl3 in a mixture of solvents toluene/triethylamine for 4 h. The p(v) triphyrin(2.1.1)s were characterized by high-resolution mass spectrometry (hrms) and nuclear magnetic resonance (nmr) spectroscopy and their properties were studied in detail by absorption, electrochemical, and density functional theory (dft) studies. The studies suggested that pcl3 reduces 14πtriphyrins to 16πtriphyrins, which were then complexed to form stable antiaromatic p(v) complexes. © |
en_US |
| dc.language.iso |
English |
en_US |
| dc.publisher |
American Chemical Society |
en_US |
| dc.subject.other |
Absorption spectroscopy |
en_US |
| dc.subject.other |
Chlorine compounds |
en_US |
| dc.subject.other |
Density functional theory |
en_US |
| dc.subject.other |
Mass spectrometry |
en_US |
| dc.subject.other |
Nuclear magnetic resonance spectroscopy |
en_US |
| dc.subject.other |
Organic solvents |
en_US |
| dc.subject.other |
Free base |
en_US |
| dc.subject.other |
High resolution mass spectrometry |
en_US |
| dc.subject.other |
Mixture of solvents |
en_US |
| dc.subject.other |
Nuclear magnetic resonance(NMR) |
en_US |
| dc.subject.other |
Refluxing |
en_US |
| dc.subject.other |
Triphyrin |
en_US |
| dc.subject.other |
Nuclear magnetic resonance |
en_US |
| dc.subject.other |
aromatic compound |
en_US |
| dc.subject.other |
phosphorus derivative |
en_US |
| dc.subject.other |
porphyrin derivative |
en_US |
| dc.subject.other |
toluene |
en_US |
| dc.subject.other |
triethylamine |
en_US |
| dc.subject.other |
triphyrin |
en_US |
| dc.subject.other |
unclassified drug |
en_US |
| dc.subject.other |
absorption spectroscopy |
en_US |
| dc.subject.other |
Article |
en_US |
| dc.subject.other |
complex formation |
en_US |
| dc.subject.other |
controlled study |
en_US |
| dc.subject.other |
density functional theory |
en_US |
| dc.subject.other |
electrochemical analysis |
en_US |
| dc.subject.other |
mass spectrometry |
en_US |
| dc.subject.other |
molecular stability |
en_US |
| dc.subject.other |
nuclear magnetic resonance spectroscopy |
en_US |
| dc.title |
Switching of Aromatic Free Base Triphyrin(2.1.1) to Antiaromatic Phosphorus(V) Complexes of Triphyrin(2.1.1) |
en_US |
| dc.type |
Article |
en_US |