Browsing Review by Subject "N,O Ligands"

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2,5-dioxido-1,4-benzoquinonediimine (h2l2-), a hydrogen-bonding noninnocent bridging ligand related to aminated topaquinone: different oxidation state distributions in complexes [{(bpy)(2)ru}(2)(mu-h2l)](n) (n=0,+,2+,3+,4+) and [{(acac)(2)ru}(2)(mu-h2l)](m) (m=2-,-,0,+,2+)

KAR, S; SARKAR, B; GHUMAAN, S; JANARDANAN, D; VAN SLAGEREN, J; FIEDLER, J; PURANIK, VG; SUNOJ, RB; KAIM, W; LAHIRI, GK (WILEY-V C H VERLAG GMBH, 2005)

The symmetrically dinuclear title compounds were isolated as diamagnetic [(bpy)(2)Ru(mu-H2L)Ru(bpy)(2)]- (ClO4)(2) (1-(ClO4)(2)) and as paramagnetic [(acac)(2)Ru(mu-H2L)Ru(acac)(2)] (2) complexes (bpy = 2,2'-bipyridine; ...
Stabilization of {runo}(6) and {runo}(7) states in [ru(ii)(trpy)(bik)(no)](n+) {trpy=2,2 ':6 ',2 ''-terpyridine, bik=2,2 '-bis(1-methylimidazolyl) ketone} - formation, reactivity, and photorelease of metal-bound nitrosyl

DE, P; SARKAR, B; MAJI, S; DAS, AK; BULAK, E; MOBIN, SM; KAIM, W; LAHIRI, GK (WILEY-V C H VERLAG GMBH, 2009)

Ruthenium nitrosyl complexes have been isolated in the {RuNO}(6) and {RuNO}(7) configurations, employing the following reaction pathway for [Ru(trpy)(bik)(X)](n+): X = Cl(-), [1](ClO(4)) -> X = CH(3)CN, [2](ClO(4))(2) -> ...

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