Exo-metallacycles have become the key reaction intermediates in activating various remote c(sp2)-h and c(sp3)-h bonds in the past decade and aided in achieving unusual site-selectivity. Various novel exo-chelating auxiliaries ...

Sequential, domino and tandem reactions could be defined as a sequence of synthetic transformations that occur one after the other, in the same reaction flask. This Review highlights recent advances at the overlap of two ...

In the past few decades, synthetic organic chemistry has been invigorated with the development of transition metal catalyzed directing group assisted regioselective C-H functionalization. Although this approach started its ...

Transition metal catalysis has contributed immensely to c-c bond formation reactions over the last few decades, and alkylation is no exception. The superiority of such methodologies over traditional alkylation is evident ...

Alkynylation reactions are one of the most sought-after synthetic methodologies due to the versatility of c−c triple bond diversifications. Sonogashira coupling was widely used for the synthesis of alkynylated molecules; ...

Spatiotemporal patterns reported to form in the cross sections of packed-bed reactors (PBRs) may pose severe safety hazard when present next to the reactor wall. Understanding what causes their formation and dynamic features ...

Appreciable advancement of low-temperature combustion processing brings a step closer to the fulfillment of large-area, flexible electronics. The maximum temperature of deposition is successfully reduced below the softening ...

Rheumatoid Arthritis (RA), one of the leading causes of disability due to progressive autoimmune destruction of synovial joints, affects similar to 1% of the global population. Standard therapy helps in reducing inflammation ...

Cancer cells undergo metabolic alterations to meet the immense demand for energy, building blocks, and redox potential. Tumors show glucose-avid and lactate-secreting behavior even in the presence of oxygen, a process known ...

Molecular tunnels regulate delivery of substrates/intermediates in enzymes which either harbor deep-seated reaction centers or are for transport of reactive/toxic intermediates that need to be specifically delivered. Here, ...