• Process intensification of dendritic fibrous nanospheres of silica (DFNS) via continuous flow: a scalable and sustainable alternative to the conventional batch synthesis 

  VEERAMANI K.; NAYAK N.; CAMERON N.R.; KUMAR A. (Royal Society of Chemistry, 2022)

  In this manuscript, we report the scalable continuous flow synthesis of dendritic fibrous nanospheres of silica (dfns) which have been speedily making a significant mark in the world of heterogeneous nanocatalysis for over ...
• Role of Delta-Notch signalling molecules on cell-cell adhesion in determining heterogeneous chemical and cell morphological patterning 

  BAJPAI S.; CHELAKKOT R.; PRABHAKAR R.; INAMDAR M.M. (Royal Society of Chemistry, 2022)

  Cell mechanics and motility are responsible for collective motion of cells that result in overall deformation of epithelial tissues. On the other hand, contact-dependent cell-cell signalling is responsible for generating ...
• Directing group assisted rhodium catalyzed meta-C-H alkynylation of arenes 

  SASMAL S.; PRAKASH G.; DUTTA U.; LASKAR R.; LAHIRI G.K.; MAITI D. (Royal Society of Chemistry, 2022)

  Site-selective c-h alkynylation of arenes to produce aryl alkynes is a highly desirable transformation due to the prevalence of aryl alkynes in various natural products, drug molecules and in materials. To ensure site-selective ...
• Synthesis of the β-dipyrrinyl triphyrin(2.1.1) ligand and its coordination complexes 

  KAUR G.; RAVIKANTH M. (Royal Society of Chemistry, 2022)

  Functionalized β-formylphenyl triphyrin(2.1.1) was prepared by coupling β-bromo triphyrin(2.1.1) with 4-formylphenyl boronic acid under pd(0) coupling conditions. Β-formylphenyl triphyrin(2.1.1) was treated with excess ...
• An unusual mixed-valence cobalt dimer as a catalyst for the anti-Markovnikov hydrophosphination of alkynes 

  KUMAR P.; SEN A.; RAJARAMAN G.; SHANMUGAM M. (Royal Society of Chemistry, 2022)

  The reaction of [co(pme3)4] (1) with a redox-active nnn pincer ligand (l1) led us to isolate a unique binuclear cobalt complex ([(pme3)2coii(l13−)coi(pme3)3] (2)) anchored by a three-electron reduced l1 in its unusual ...
• Solid-state photochromic arylazopyrazole-based transition metal complexes 

  GUPTA D.; GAUR A.K.; CHAUHAN D.; THAKUR S.K.; JEYAPALAN V.; SINGH S.; RAJARAMAN G.; VENKATARAMANI S. (Royal Society of Chemistry, 2022)

  A new class of photoactive and chelating ligands l1-3 has been designed and synthesized by incorporating arylazo-3,5-dimethylpyrazole units in the ligand frameworks. Significantly, they are designed in such a way that ...
• A unique and discrete Ce(iii) macrocyclic complex exhibits ferroelectric, dielectric, and slow relaxation of magnetization properties 

  WASIM M.; ANSARI K.U.; KUMAR P.; MALLICK B.; SHANMUGAM M. (Royal Society of Chemistry, 2022)

  A discrete [ce(l1)(no3)3] (1; l1 = macrocyclic schiff base ligand) complex exhibits both ferroelectricity and magnetic bistability together, which is extremely rare and challenging to achieve. The presence of the second ...
• Supramolecular aggregation in sterically encumbered monoarylphosphates and their H-bonded adducts: multigram synthesis of elusive 2,6-di-tert-butylphenyl phosphate 

  PRAPAKARAN T.; KUPPUSWAMY S.; MURUGAVEL R. (Royal Society of Chemistry, 2022)

  Sterically encumbered 2,6-di-tert-butylphenyl phosphate (dtbpph2) (1) has been synthesized in two steps from the reaction of either the lithium or sodium salt of 2,6-di-tert-butylphenol with pocl3, followed by controlled ...
• Understanding the mechanism and kinetics of the formation and breaking of ring structures during silica polymerization: a computational study 

  SHERE I.; MALANI A. (Royal Society of Chemistry, 2022)

  Ring structures are ubiquitous in porous materials and play a crucial role in the functioning of these materials. Understanding the ring formation and breaking mechanism is essential for designing and controlling the ...
• Synthesis and characterization of templatemediated mesoporous alumina nanostructures with efficient and fast adsorption of Congo red from aqueous solutions 

  MISHRA G.; DAS S.; JENA P.; DASH B. (Royal Society of Chemistry, 2022)

  This article summaries an approach for the removal of organic dyes like congo red using mesoporous alumina. Industrial effluents that contain dyes need to be treated before being discharged into surface water. The adsorption ...
• Quantum interference effects elucidate triplet-pair formation dynamics in intramolecular singlet-fission molecules 

  PARENTI K.R.; CHESLER R.; HE G.; BHATTACHARYYA P.; XIAO B.; HUANG H.; MALINOWSKI D.; ZHANG J.; YIN X.; SHUKLA A.; MAZUMDAR S.; SFEIR M.Y.; CAMPOS L.M. (Nature Research, 2022)

  Quantum interference (qi)—the constructive or destructive interference of conduction pathways through molecular orbitals—plays a fundamental role in enhancing or suppressing charge and spin transport in organic molecular ...
• Copper-Plumbagin Complex Produces Potent Anticancer Effects by Depolymerizing Microtubules and Inducing Reactive Oxygen Species and DNA Damage 

  MUKHERJEE S.; SAWANT A.V.; PRASSANAWAR S.S.; PANDA D. (American Chemical Society, 2022)

  Here, we have synthesized a copper complex of plumbagin (cu-pln) and investigated its antiproliferative activities in different cancer cells. The crystal structure of cu-pln showed that the complex was square planar with ...
• Nontoxic in Vivo Clearable Nanoparticle Clusters for Theranostic Applications 

  YADAV P.; MIMANSA; MUNAWARA R.; KAPOOR K.; CHATURVEDI S.; KAILASAM K.; BISWAS S.K.; BAHADUR D.; SRIVASTAVA R.; MISHRA A.K.; SHANAVAS A. (American Chemical Society, 2021)

  Disintegrable inorganic nanoclusters (gions) with gold seed (gs) coating of an iron oxide core with a primary nanoparticle size less than 6 nm were prepared for theranostic applications. The gions possessed a broad ...
• Pathway Complexity in Supramolecular Copolymerization and Blocky Star Copolymers by a Hetero-Seeding Effect 

  KHANRA P.; SINGH A.K.; ROY L.; DAS A. (American Chemical Society, 2022)

  This study unravels the intricate kinetic and thermodynamic pathways involved in the supramolecular copolymerization of the two chiral dipolar naphthalene monoimide (nmi) building blocks (o-nmi and s-nmi), differing merely ...
• Understanding the Effects of Tetrahedral Site Occupancy by the Zn Dopant in Li-NMCs toward High-Voltage Compositional-Structural-Mechanical Stability via Operando and 3D Atom Probe Tomography Studies 

  SHARMA A.; PANDEY A.H.; JANGID M.K.; SRIHARI V.; POSWAL H.K.; MUKHOPADHYAY A. (American Chemical Society, 2022)

  Ni-containing "layered"/cation-ordered litmo2s (tm = transition metal) suffer from ni-migration to the li-layer at the unit cell level, concomitant transformation to a spinel/rock salt structure, hindrance toward li-transport, ...
• Demonstration of Synaptic Behavior in a Heavy-Metal-Ferromagnetic-Metal-Oxide-Heterostructure-Based Spintronic Device for On-Chip Learning in Crossbar-Array-Based Neural Networks 

  YADAV R.S.; GUPTA P.; HOLLA A.; ALI KHAN K.I.; MUDULI P.K.; BHOWMIK D. (American Chemical Society, 2022)

  Nanomagnetic and spintronic devices, which make use of physical phenomena in materials and interfaces like perpendicular magnetic anisotropy (pma) and spin-orbit torque (sot) to exhibit multiple electrically readable and ...
• Photonic Cured Metal Oxides for Low-Cost, High-Performance, Low-Voltage, Flexible, and Transparent Thin-Film Transistors 

  SARKAR S.K.; MAJI D.; KHAN J.A.; KURUP S.; GUPTA D. (American Chemical Society, 2022)

  Flash light-based photonic curing has recently emerged as a promising technique for low-cost and ultrafast production of flexible electronics. In this work, we demonstrate photonic curing-based low-cost fabrication of ...
• Microfluidics Based Generation of Curcumin Loaded Microfibrous Mat against Staphylococcus aureus Biofilm by Photodynamic Therapy 

  SHARMA K.; PANDEY S.; SEKAR H.; ALAN T.; GUNDABALA V. (American Chemical Society, 2022)

  The rapid increase in multidrug resistant biofilm infections is a major concern for global health. A highly effective therapy is required for the treatment of biofilm related infections. In this study, curcumin loaded ...
• Integrative Proteomic and Pharmacological Analysis of Colon Cancer Reveals the Classical Lipogenic Pathway with Prognostic and Therapeutic Opportunities 

  BARPANDA A.; BISWAS D.; VERMA A.; PARIHARI S.; SINGH A.; KAPOOR S.; KANTHARIA C.; SRIVASTAVA S. (American Chemical Society, 2022)

  Despite recent advancements, the high mortality rate remains a concern in colon cancer (cac). Identification of therapeutic markers could prove to be a great asset in cac management. Multiple studies have reported ...
• Regioselective Disulfide-Catalyzed Photocatalytic Oxidative Cleavage of 1-Arylbutadienes to Cinnamaldehydes 

  FERNANDES R.A.; KUMAR P.; BHOWMIK A.; GORVE D.A. (American Chemical Society, 2022)

  This work discloses a simple, efficient, and environmentally benevolent disulfide-catalyzed photocatalytic regioselective oxidative cleavage of 1-arylbutadienes to cinnamaldehydes. This methodology illustrates mild reaction ...

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