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dc.contributor.authorKUNDU, Aen_US
dc.contributor.authorKISHORE, Nen_US
dc.date.accessioned2011-08-17T10:52:32Zen_US
dc.date.accessioned2011-12-26T12:55:30Zen_US
dc.date.accessioned2011-12-27T05:40:49Z
dc.date.available2011-08-17T10:52:32Zen_US
dc.date.available2011-12-26T12:55:30Zen_US
dc.date.available2011-12-27T05:40:49Z
dc.date.issued2002en_US
dc.identifier.citationJOURNAL OF SOLUTION CHEMISTRY, 31(6), 477-498en_US
dc.identifier.issn0095-9782en_US
dc.identifier.urihttp://dx.doi.org/10.1023/A:1020269629589en_US
dc.identifier.urihttp://dspace.library.iitb.ac.in/xmlui/handle/10054/9841en_US
dc.identifier.urihttp://hdl.handle.net/10054/9841
dc.description.abstractPartial molar volumes of cytosine, uracil, thymine, cytidine, uridine, thymidine, and adenosine have been measured in different concentrations of aqueous ethanol, 1,2-ethanediol, 2-propanol, and 2-methyl-2-propanol at 25degreesC using densimetry. These data are utilized in conjunction with the partial molar volumes of these nucleic acid bases and nucleosides in water reported earlier to deduce the partial molar volumes of transfer from water to aqueous alcohol or diol. The results are explained in terms of likely solute-solvent interactions; the role of solvent in these interactions is discussed. The partial molar volume data are also used to calculate the contribution of -CH2- groups in the nucleic acid base or solvent and of ribose in the nucleoside to the partial molar volume of transfer. The validity of group additivity in these systems is discussed.en_US
dc.language.isoenen_US
dc.publisherKLUWER ACADEMIC/PLENUM PUBLen_US
dc.subjectPartial Molal Volumesen_US
dc.subjectHeat-Capacitiesen_US
dc.subjectTransfer Energeticsen_US
dc.subject298.15 Ken_US
dc.subjectWateren_US
dc.subjectDnaen_US
dc.subjectAlcoholsen_US
dc.subjectMixturesen_US
dc.subjectStabilityen_US
dc.subjectHydrationen_US
dc.subject.otherNucleic Acid Basesen_US
dc.subject.otherNucleosidesen_US
dc.subject.otherPartial Molar Volumeen_US
dc.subject.otherEthanolen_US
dc.subject.other1,2-Ethanediolen_US
dc.subject.other2-Propanolen_US
dc.subject.other2-Methyl-2-Propanolen_US
dc.titleVolumetric properties of nucleic acid bases and nucleosides in aqueous ethanol, 1,2-ethanediol, 2-propanol, and 2-methyl-2-propanol at 25 degrees Cen_US
dc.typeArticleen_US


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