π4s+π2s Cycloaddition between electron deficient π-systems and photoreaction of β,γ-enones: a novel stereoselective entry into angular triquinanes

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π4s+π2s Cycloaddition between electron deficient π-systems and photoreaction of β,γ-enones: a novel stereoselective entry into angular triquinanes

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Title: π4s+π2s Cycloaddition between electron deficient π-systems and photoreaction of β,γ-enones: a novel stereoselective entry into angular triquinanes
Author: SINGH, VISHWAKARMA; LAHIRI, SANJOY
Abstract: Cycloaddition of electron deficient partners such as cyclohexa-2,4-dienone and acrylates leading to an efficient synthesis of complex bicyclo[2.2.2]octenones having a β,γ-enone chromophore, and their transformation to angular triquinanes via photoreaction, is described.
URI: http://dx.doi.org/10.1016/S0040-4039(03)00887-6
http://hdl.handle.net/10054/844
http://dspace.library.iitb.ac.in/xmlui/handle/10054/844
Date: 2003


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