[5+3] Cycloaddition of 3-Oxidopyrylium: A Novel Route to Functionalized Cyclooctanoids from Furans

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[5+3] Cycloaddition of 3-Oxidopyrylium: A Novel Route to Functionalized Cyclooctanoids from Furans

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Title: [5+3] Cycloaddition of 3-Oxidopyrylium: A Novel Route to Functionalized Cyclooctanoids from Furans
Author: KRISHNA, UM; PATIL, MP; SUNOJ, RB; TRIVEDI, GK
Abstract: We report a facile and efficient synthesis of highly functionalized cyclooctanoid derivatives by employing a dimerization reaction of 3-oxidopyrylium ylides. Different substituents are introduced on the dimer and the stereochemical outcome of the resultant cyclooctanoids is unambiguously established by single-crystal Xray analysis.
URI: http://dx.doi.org/10.1055/s-0029-1217092
http://dspace.library.iitb.ac.in/xmlui/handle/10054/7893
http://hdl.handle.net/10054/7893
Date: 2010


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