A novel dimeric copper salicylate with an undissociated COOH group: Synthesis and crystal structure of [Cu-2(HSal)(Sal)(2,2 '-bpy)(2)](ClO4)

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A novel dimeric copper salicylate with an undissociated COOH group: Synthesis and crystal structure of [Cu-2(HSal)(Sal)(2,2 '-bpy)(2)](ClO4)

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Title: A novel dimeric copper salicylate with an undissociated COOH group: Synthesis and crystal structure of [Cu-2(HSal)(Sal)(2,2 '-bpy)(2)](ClO4)
Author: PALANISAMI, N; PRABUSANKAR, G; MURUGAVEL, R
Abstract: A dinuclear copper salicylate [Cu-2(HSal)(Sal)(2,2'-bpy)(2)](ClO4) (1) (H(2)Sal = salicylic acid) has been synthesized and characterized with the aid of elemental analysis and infrared, ultraviolet and fluorescence spectroscopic studies. The molecular structure of 1, determined by single-crystal X-ray diffraction studies, shows the presence of incompletely deprotonated salicylate ligands in the complex. Hydrogen bonding interactions and pi-pi aromatic stacking lead to the formation of 2D polymeric structure in the solid state. (C) 2006
URI: http://dx.doi.org/10.1016/j.inoche.2006.05.025
http://dspace.library.iitb.ac.in/xmlui/handle/10054/6333
http://hdl.handle.net/10054/6333
Date: 2006


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