A double helix is the repeating unit in a luminescent calcium 5-aminoisophthalate supramolecular edifice with water-filled hexagonal channels

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A double helix is the repeating unit in a luminescent calcium 5-aminoisophthalate supramolecular edifice with water-filled hexagonal channels

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Title: A double helix is the repeating unit in a luminescent calcium 5-aminoisophthalate supramolecular edifice with water-filled hexagonal channels
Author: MURUGAVEL, R; KUMAR, P; WALAWALKAR, MG; MATHIALAGAN, R
Abstract: Calcium 5-aminoisophthalate {[Ca(AlP)(OH2)(4)](H2O)}infinity (1), synthesized from Ca(OH)2 and HAP, exists as a double helix. Hydrogen-bonding interactions between metal-bound water molecules, carboxylate oxygen, and the -NH2 group result in the formation of a supramolecular assembly, where the double helices are connected to each other to form hexagonal channels filled with water molecules.
URI: http://dx.doi.org/10.1021/ic070113k
http://dspace.library.iitb.ac.in/xmlui/handle/10054/3683
http://hdl.handle.net/10054/3683
Date: 2007


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