CONVENIENT SYNTHESIS OF DECALIN SYSTEMS OF BIOACTIVE TERPENOIDS

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CONVENIENT SYNTHESIS OF DECALIN SYSTEMS OF BIOACTIVE TERPENOIDS

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Title: CONVENIENT SYNTHESIS OF DECALIN SYSTEMS OF BIOACTIVE TERPENOIDS
Author: GORE, VK; DESAI, SR; MAYELVAGANAN, T; PADMAKUMAR, R; HADIMANI, SB; BHAT, SV
Abstract: New analogues of bioactive terpenoids, forskolin, nimbolide, isozonarol and ambrox have been synthesized using general Diels-Alder reaction of 2-formyl-4,4-dimethyl-cyclohexa-2,5-dienone (7) with 1,2-disubstituted-1,3-dienes (8a-k) which yielded endo- & exo-adducts. The deformylation, epimerisation, angular methylation, reduction and oxidation studies on these adducts have been reported.
URI: http://dx.doi.org/10.1016/S0040-4020(01)86353-5
http://dspace.library.iitb.ac.in/xmlui/handle/10054/10639
http://hdl.handle.net/10054/10639
Date: 1993


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