Transition metal chemistry of phosphorus based ligands: synthesis and transition metal chemistry of N,N′-dimethyl,-bis(diphenylphosphino)ethylenediamine. The crystal and molecular structure of [ReBr(CO)3{Ph2PN(Me)CH2CH2(Me)NPPh2}]

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Transition metal chemistry of phosphorus based ligands: synthesis and transition metal chemistry of N,N′-dimethyl,-bis(diphenylphosphino)ethylenediamine. The crystal and molecular structure of [ReBr(CO)3{Ph2PN(Me)CH2CH2(Me)NPPh2}]

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Title: Transition metal chemistry of phosphorus based ligands: synthesis and transition metal chemistry of N,N′-dimethyl,-bis(diphenylphosphino)ethylenediamine. The crystal and molecular structure of [ReBr(CO)3{Ph2PN(Me)CH2CH2(Me)NPPh2}]
Author: BALAKRISHNA, MS; WALAWALKAR, MRINALINI G
Abstract: The bis(phosphine), Ph2PN(CH3)CH2CH2N(CH3)PPh2 reacts with Group 6 metal carbonyl derivatives, [ReBr(CO)3(NCMe)2] and [MCl2(COD)] (M=Pd or Pt) to give the corresponding seven-membered chelate complexes. The compounds have been characterized by elemental analysis, IR and NMR spectroscopic data. The structure of the rhenium complex, [ReBr(CO)3{Ph2PN(CH3)CH2CH2(CH3)NPPh2}] has been confirmed by X-ray crystallography.
URI: http://dx.doi.org/10.1016/S0022-328X(01)00764-1
http://hdl.handle.net/10054/1003
http://dspace.library.iitb.ac.in/xmlui/handle/10054/1003
Date: 2001


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