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|Title:||Dimeric Pyranonaphthoquinones: Isolation, Bioactivity, and Synthetic Approaches|
|Keywords:||Konstitution Des Actinorhodins|
Enantiodivergent Total Syntheses
Short Enantioselective Synthesis
Double Furofuran Annulation
|Publisher:||WILEY-V C H VERLAG GMBH|
|Citation:||EUROPEAN JOURNAL OF ORGANIC CHEMISTRY,(35)5778-5798|
|Abstract:||The dimeric pyranonaphthoquinones, bis versions of the naphtho[2,3-c]pyran-5,10-dione moiety, comprises a group of antibiotics that have been isolated from a variety of sources including plants, bacteria, fungi, and insects. This review discusses the known naturally occurring dimeric pyranonaphthoquinones, their isolation and bioactivity, and synthetic approaches towards them that have helped to confirm their structures, as well as to resolve structural uncertainties such as stereochemistry. The major focus has been on the synthetic approaches adopted to complete the challenging total synthesis of the natural isolates and analogues.|
|Appears in Collections:||Review|
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