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|Title:||A concise synthesis of (4R,5R)-(-)-muricatacin and (4R,5R)-L-(-)-factor from D-glucono-delta-lactone|
Hagens Gland Lactones
|Publisher:||PERGAMON-ELSEVIER SCIENCE LTD|
|Abstract:||A concise seven-step synthesis of (4R,5R)-(-)-muricatacin and (4R,5R)-L-(-)-factor from inexpensive, commercially available D-glucono-delta-lactone has been accomplished. The keys steps involve a one-pot conversion of the latter to gamma-vinyl-gamma-lactone, cross-metathesis and Wittig olefination. This strategy has potential for the synthesis of analogs by changing the alkyl side chain by Wittig olefination. (C) 2016 Elsevier Ltd. All rights reserved.|
|Appears in Collections:||Article|
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