DSpace at IIT Bombay >
IITB Publications >
Please use this identifier to cite or link to this item:
|Title: ||(Z)-Diiodo(2-iodo-2-phenylvinyl)(phenyl)tellurium PhIC=CHTeI2Ph: Synthesis and Complexing Properties in a Reaction with Iron Pentacarbonyl|
|Authors: ||TORUBAEV, YV|
|Issue Date: ||2008|
|Publisher: ||MAIK NAUKA/INTERPERIODICA/SPRINGER|
|Citation: ||RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 34(11), 805-810|
|Abstract: ||Electrophilic addition of PhTeI3 to phenylacetylene (PhC2H) in boiling THF stereoselectively gave (Z)-diiodo(2-iodo-2-phenylvinyl)(phenyl)tellurium PhIC=CHTeI2Ph (I). In a reaction with Fe(CO)(5), this complex easily eliminated two iodine atoms from tellurium to give PhTe-CH=CPhI. This ligand was coordinated to iron in a monodentate fashion through the Te atom in the resulting complex (CO)(3)FeI2(PhTeHC=CPhI) (II). The reaction also yielded the known complex Fe(CO)(4)I-2 (III). The structures of complexes I-III were determined by X-ray diffraction analysis. The Fe-Te bond in structure II is substantially shortened.|
|Appears in Collections:||Article|
Files in This Item:
There are no files associated with this item.
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.