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Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/jspui/handle/10054/9826

Title: Diacetylenic derivatives of Fe-2(CO)(6)(mu-EE '): Spectroscopic investigations of Fe-2(CO)(6){mu-EC(H)=C(C CMe)E '} (E = E ', E not equal E '; E, E ' = S, Se, Te)
Authors: MATHUR, P
DASH, AK
Keywords: acetylenic bond reduction
mixed-metal
structural characterization
crystal-structure
clusters
chalcogenide
complexes
ligands
fe2(co)6(mu-se2)
phenylacetylene
Issue Date: 1998
Publisher: KLUWER ACADEMIC/PLENUM PUBL
Citation: JOURNAL OF CLUSTER SCIENCE, 9(2), 131-143
Abstract: The diacetylenic adducts, Fe-2(CO)(6){mu-EC(H) = C(C = CMe)E'} (E = E' and E not equal E'; E, E' = S, Se, Te) (1-8) have been obtained from the room temperature stirring of Fe-2(CO)(6)(mu-EE') with HC = CC = CMe in methanol solvent containing sodium acetate. Compounds 1-8 have been characterized by IR and multinuclear NMR (H-1, C-13, Se-77, and Te-125) spectroscopy. Trends in the chemical shifts of Se-77 and (12)5Te NMR spectra of Fe-2(CO)(6){mu-EC(H) = C(C = CMe)E'} with a variation of EE' are discussed.
URI: http://dx.doi.org/10.1023/A:1021937931974
http://dspace.library.iitb.ac.in/xmlui/handle/10054/9826
http://hdl.handle.net/10054/9826
ISSN: 1040-7278
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