Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/xmlui/handle/10054/9825
Title: Catalytic oxidation of alkylaromatics over mesoporous (Cr)MCM-41
Authors: SAKTHIVEL, A
BADAMALI, SK
SELVAM, P
Keywords: Diffuse-Reflectance Spectroscopy
Molecular-Sieves
Selective Oxidation
Liquid-Phase
Chromium
Alcohols
Mcm-41
Silica
Tbhp
Issue Date: 2002
Publisher: KLUWER ACADEMIC/PLENUM PUBL
Citation: CATALYSIS LETTERS, 80(1-2), 73-76
Abstract: Liquid-phase catalytic oxidation of certain alkylaromatics over mesoporous (Cr)MCM-41 molecular sieves in the presence of chlorobenzene and tertiary butylhydroperoxide showed high substrate conversion and excellent product selectivity. The high catalytic activity of the materials is attributed to the complete oxidation of chromium ions to hexavalent chromium and the absence of pentavalent chromium in the mesoporous matrix.
URI: http://dx.doi.org/10.1023/A:1015330827806
http://dspace.library.iitb.ac.in/xmlui/handle/10054/9825
http://hdl.handle.net/10054/9825
ISSN: 1011-372X
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