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Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/jspui/handle/10054/9811

Title: Synthesis, spectroscopy and electrochemistry of mixed-ligand complexes of platinum(II) and palladium(II)
Authors: ANBALAGAN, V
SRINIVASAN, R
PALLAVI, KS
Keywords: alpha-diimine complexes
charge-transfer
photoluminescence
2,2'-bipyridine
luminescent
bipyridine
azide
Issue Date: 2001
Publisher: KLUWER ACADEMIC PUBL
Citation: TRANSITION METAL CHEMISTRY, 26(6), 603-607
Abstract: Mixed-ligand complexes [MX2(MBPY)] (M = Pd-I(I) or Pt-I(I); X = Cl-, I-, N-3(-) or NO2-; MBPY = 4,4'-dimethyl-2,2'-bipyridine) have been prepared and characterised by elemental analyses, conductivity measurements, i.r., electronic absorption and H-1-n.m.r. spectroscopic techniques. The cyclic voltammograms of these complexes suggest the involvement of the metal d pi orbital in the one-electron oxidation process and the pi* orbital of the MBPY in the one-electron reduction process. [Pt(MBPY)(N-3)(2)] shows solution-state luminescence at room temperature.
URI: http://dx.doi.org/10.1023/A:1012095807566
http://dspace.library.iitb.ac.in/xmlui/handle/10054/9811
http://hdl.handle.net/10054/9811
ISSN: 0340-4285
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