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| Title: | Formation of 5-phenyl-1,2-dithiole-3-thione from molybdenum dithiopropiolato complexes |
| Authors: | MATHUR, PRADEEP
AVASARE, VIDYA D
GHOSH, ABHIJIT K
SHAIKH, MOBIN M |
| Keywords: | allergies
thermolysis
carbonylation |
| Issue Date: | 2004 |
| Publisher: | Elsevier |
| Citation: | Journal of Organometallic Chemistry 689(7), 1325-1327 |
| Abstract: | Molybdenum dithiopropiolato complexes, [(η5-C5R4R′)Mo(CO)2(η2-S2CC≡CPh)] (R=H, R=Me 1a, R=R′=H 1b; R=R′=Me 1c) react with trimethylamine-N-oxide (TMNO · 2H2O) under mild thermolysis to form 5-phenyl-1,2-dithiole-3-thione (2). The reaction proceeds through the formation of the oxo-complexes, [(η5-C5R4R′)Mo(O)(η3-S2CC≡CPh)] (R=H, R′=Me 3a, R=R′=H 3b; R=R′=Me 3c). Direct reaction of 3a–c with TMNO · 2H2O under thermolysis also results in formation of 2. |
| URI: | http://dx.doi.org/10.1016/j.jorganchem.2004.01.022
http://hdl.handle.net/10054/866
http://dspace.library.iitb.ac.in/xmlui/handle/10054/866 |
| ISSN: | 0022-328X |
| Appears in Collections: | Article
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