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Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/jspui/handle/10054/8646

Title: Fluorescence properties of meso-tetrafurylporphyrins
Authors: GUPTA, I
Keywords: excited-state properties
photophysical properties
nonplanar porphyrins
Issue Date: 2005
Citation: JOURNAL OF CHEMICAL SCIENCES, 117(2), 161-166
Abstract: Fluorescence properties of meso-tetrafurylporphyrins with N-4, N3S and N2S2 porphyrin cores are studied by both steady-state and time-resolved fluorescence techniques and compared with the corresponding meso-tetraarylporphyrins. The study shows that the replacement of six-membered aryl groups with five-membered furyl groups at meso-positions alter the fluorescence properties considerably, as reflected in the large red shifts and broadening of fluorescence bands with reduction in quantum yields and singlet excited-state lifetimes. However, zinc(II) derivatives of meso-tetrafurylporphyrin and meso-tetraarylporphyrin did not show significant differences in their emission properties.
URI: http://dspace.library.iitb.ac.in/xmlui/handle/10054/8646
ISSN: 0253-4134
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