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Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/jspui/handle/10054/8573

Title: Suzuki-Miyaura, Mizoroki-Heck carbon carbon coupling and hydrogenation reactions catalysed by Pd(II) and Rh(I) complexes containing cyclodiphosphazane cis-{(t)BuNP(OC(6)H(4)OMe-o)}(2)
Authors: MOHANTY, S
BALAKRISHNA, MS
Keywords: metal-complexes
aryl bromides
copper(i) coordination
reversible conversion
ligands
phosphinite
chemistry
ruthenium(ii)
chlorides
bearing
Issue Date: 2010
Publisher: INDIAN ACAD SCIENCES
Citation: JOURNAL OF CHEMICAL SCIENCES, 122(2), 137-142
Abstract: The catalytic activity of the palladium complex cis-[PdCl(2)f((t)BuNP(OC(6)H(4)OMe-o))(2)-KP}(2)] (2) containing cis-{(t)BuNP(OC(6)H(4)OMe-o)}(2) (1) in Suzuki Miyaura and Mizoroki Heck carbon carbon cross coupling reactions is described. The compound 2 also displays very high activity in Mizoroki Heck coupling reactions. The rhodium(I) complex [RhCl(COD)(((t)BuNP(OC(6)H(4)OMe-o))(2)-kappa P] (3) acts as an excellent catalyst for the hydrogenation of several terminal olefins.
URI: http://dspace.library.iitb.ac.in/xmlui/handle/10054/8573
http://hdl.handle.net/10054/8573
ISSN: 0253-4134
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