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Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/jspui/handle/10054/826

Title: Recognition of oxovanadium(V) species and its separation from other metal species through selective complexation by some acyclic ligands
Authors: RAO, CHEBROLU P
SREEDHARA, A
VENKATESWARA RAO, P
LOKANATH, NK
SRIDHAR, MA
PRASAD, JS
KARI RISSANEN
Keywords: electronic
absorption spectra
synthesis
crystallographic
Issue Date: 1998
Publisher: Elsevier
Citation: Polyhedron 18(1-2), 289-297
Abstract: Acyclic molecules possessing –OH (phenoxo and alkoxo type) groups and imine or amine moieties have been developed to sense the specific preference for VO3+ species. These molecules also showed a capability to quantitatively separate oxovanadium(V) species from a reaction mixture containing metal species of V, Mo, U, Fe, and Mn ions in solution. A cascade quantitative separation of VO3+ followed by cis–MoO2+2 followed by trans –UO2+2 species is demonstrated from their mixture. Synthesis and structural details of oxo-species of vanadium molybdenum and uranium are also discussed. Factors influencing the complexation of these molecules towards oxo metal species of V, Mo and U are also addressed.
URI: http://dx.doi.org/10.1016/S0277-5387(98)00298-8
http://hdl.handle.net/10054/826
http://dspace.library.iitb.ac.in/xmlui/handle/10054/826
ISSN: 0277-5387
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