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|Title:||COPOLYMERIZATION OF TRI-NORMAL-BUTYLTIN-ALPHA-CHLOROACRYLATE WITH 2-HYDROXYALKYL METHACRYLATES|
|Publisher:||HUTHIG & WEPF VERLAG|
|Citation:||ANGEWANDTE MAKROMOLEKULARE CHEMIE, 189(), 1-11|
|Abstract:||Copolymers of tri-n-butyltin-alpha-chloracrylate (TCA) with 2-hydroxyethyl methacrylate (HEMA) and 2-hydroxypropyl methacrylate (HPMA) were synthesized in solution at 55-degrees-C using azobisisobutyronitrile as initiator. Copolymer compositions were determined by tin analysis. Monomer reactivity ratios were calculated by the Kelen-Tudos method. The copolymers were further characterized by IR, H-1-NMR, TGA, DSC, XRD and solubility. Biotoxicity studies of the copolymers are also reported. The copolymer system is compared with similar copolymers of tri-n-butyltin methacrylate.|
|Appears in Collections:||Article|
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