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|Title:||COPOLYMERIZATION OF ALKYL ALPHA-CHLOROACRYLATES WITH METHYL-METHACRYLATE|
|Publisher:||HUTHIG & WEPF VERLAG|
|Citation:||ANGEWANDTE MAKROMOLEKULARE CHEMIE, 184(), 147-155|
|Abstract:||Hexyl alpha-chloroacrylate (HCA) and cyclohexyl alpha-chloroacrylate (CCA) have been copolymerized with methyl methacrylate (MMA) in toluene at 55-degrees-C using azobisiso-butyronitrile (AIBN) as initiator. Copolymer compositions have been determined both by H-1 NMR and elemental analyses. For copolymerization of MMA (M1) with HCA (M2), the reactivity ratios (RR) are r1 = 0.47 +/- 0.19 and r2 = 0.81 +/- 0.51 and with CCA the values are r1 = 0.76 +/- 0.31 and r2 = 2.30 +/- 1.73. Thermal properties of these copolymers have also been investigated.|
|Appears in Collections:||Article|
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