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Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/jspui/handle/10054/7897

Title: Aromatics to Diquinanes: An Expeditious Synthesis of Tetramethylbicyclo[3.3.0]octane Framework of Ptychanolide
Authors: SINGH, V
CHANDRA, G
MOBIN, SM
Keywords: liverwort frullanoides-densifolia
ptychanthus-striatus lehm
1st total-synthesis
molecular complexity
linear triquinane
organic-synthesis
natural-products
building-blocks
lindenb nees
rearrangement
Issue Date: 2008
Publisher: GEORG THIEME VERLAG KG
Citation: SYNLETT, (20), 3111-3114
Abstract: An expeditious route to methyl-7-oxo-1,4,5,8-tetramethylbicyelo[3.3.0]octane-3-carboxylate from a simple aromatic precursor is described. Oxidative dearomatization of 2-hydroxymethyl-3,4,6-trimethylphenol into spiroepoxycycloliexa-2,4-dierone, its cycloaddition and triplet-sensitized 1,2-acyl shift, and stereochemical inversion are the key features Of Our methodology.
URI: http://dx.doi.org/10.1055/s-0028-1087275
http://dspace.library.iitb.ac.in/xmlui/handle/10054/7897
http://hdl.handle.net/10054/7897
ISSN: 0936-5214
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