Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/xmlui/handle/10054/7897
Title: Aromatics to Diquinanes: An Expeditious Synthesis of Tetramethylbicyclo[3.3.0]octane Framework of Ptychanolide
Authors: SINGH, V
CHANDRA, G
MOBIN, SM
Keywords: Liverwort Frullanoides-Densifolia
Ptychanthus-Striatus Lehm
1st Total-Synthesis
Molecular Complexity
Linear Triquinane
Organic-Synthesis
Natural-Products
Building-Blocks
Lindenb Nees
Rearrangement
Issue Date: 2008
Publisher: GEORG THIEME VERLAG KG
Citation: SYNLETT, (20), 3111-3114
Abstract: An expeditious route to methyl-7-oxo-1,4,5,8-tetramethylbicyelo[3.3.0]octane-3-carboxylate from a simple aromatic precursor is described. Oxidative dearomatization of 2-hydroxymethyl-3,4,6-trimethylphenol into spiroepoxycycloliexa-2,4-dierone, its cycloaddition and triplet-sensitized 1,2-acyl shift, and stereochemical inversion are the key features Of Our methodology.
URI: http://dx.doi.org/10.1055/s-0028-1087275
http://dspace.library.iitb.ac.in/xmlui/handle/10054/7897
http://hdl.handle.net/10054/7897
ISSN: 0936-5214
Appears in Collections:Article

Files in This Item:
There are no files associated with this item.


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.