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| Title: | [5+3] Cycloaddition of 3-Oxidopyrylium: A Novel Route to Functionalized Cyclooctanoids from Furans |
| Authors: | KRISHNA, UM
PATIL, MP
SUNOJ, RB
TRIVEDI, GK |
| Keywords: | ring-closing metathesis
intramolecular aldol condensation
carbocyclic 8-membered rings
polarizable continuum model
olefin metathesis
organic-synthesis
catalyzed cycloadditions
nitrogen-heterocycles
samarium(ii) iodide
taxane skeleton |
| Issue Date: | 2010 |
| Publisher: | GEORG THIEME VERLAG KG |
| Citation: | SYNTHESIS-STUTTGART, (2), 320-328 |
| Abstract: | We report a facile and efficient synthesis of highly functionalized cyclooctanoid derivatives by employing a dimerization reaction of 3-oxidopyrylium ylides. Different substituents are introduced on the dimer and the stereochemical outcome of the resultant cyclooctanoids is unambiguously established by single-crystal Xray analysis. |
| URI: | http://dx.doi.org/10.1055/s-0029-1217092
http://dspace.library.iitb.ac.in/xmlui/handle/10054/7893
http://hdl.handle.net/10054/7893 |
| ISSN: | 0039-7881 |
| Appears in Collections: | Article
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