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Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/jspui/handle/10054/7893

Title: [5+3] Cycloaddition of 3-Oxidopyrylium: A Novel Route to Functionalized Cyclooctanoids from Furans
Authors: KRISHNA, UM
PATIL, MP
SUNOJ, RB
TRIVEDI, GK
Keywords: ring-closing metathesis
intramolecular aldol condensation
carbocyclic 8-membered rings
polarizable continuum model
olefin metathesis
organic-synthesis
catalyzed cycloadditions
nitrogen-heterocycles
samarium(ii) iodide
taxane skeleton
Issue Date: 2010
Publisher: GEORG THIEME VERLAG KG
Citation: SYNTHESIS-STUTTGART, (2), 320-328
Abstract: We report a facile and efficient synthesis of highly functionalized cyclooctanoid derivatives by employing a dimerization reaction of 3-oxidopyrylium ylides. Different substituents are introduced on the dimer and the stereochemical outcome of the resultant cyclooctanoids is unambiguously established by single-crystal Xray analysis.
URI: http://dx.doi.org/10.1055/s-0029-1217092
http://dspace.library.iitb.ac.in/xmlui/handle/10054/7893
http://hdl.handle.net/10054/7893
ISSN: 0039-7881
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