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Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/jspui/handle/10054/782

Title: Hydroxyalkylation of conjugated nitroalkenes with activated nonenolizable carbonyl compounds
Authors: DEB, INDUBHUSAN
DADWAL, MAMTA
SHAIKH, MOBIN M
NAMBOOTHIRI, IRISHI NN
Keywords: morita-baylis hilman reaction
acetonitrile
activated carbon
conjugated
Issue Date: 2006
Publisher: American Chemical Society
Citation: Organic Letters 8, 1201-1204
Abstract: The Morita-Baylis-Hillman reaction of a variety of conjugated nitroalkenes with activated nonenolizable carbonyl compounds such as glyoxylate, trifluoropyruvate, pyruvaldehyde, and ninhydrin in the presence of 40-100 mol % of DMAP in acetonitrile or 100 mol % of imidazole in CHCl3 or THF provided the adducts in decent to good yields. In most cases, the reactions catalyzed by DMAP in acetonitrile were faster and provided the desired MBH adducts in higher yields as compared to the imidazole catalyzed reactions.
URI: http://dx.doi.org/10.1021/ol060041l
http://hdl.handle.net/10054/782
http://dspace.library.iitb.ac.in/xmlui/handle/10054/782
ISSN: 1523-7060
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