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Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/jspui/handle/10054/7764

Title: Synthesis, spectroscopic and structural characterisation of {(CO)(3)Fe(mu-CH2)Se}(2) and (CO)(6)Fe-2{mu-Se(CH2)(n)Se} (n=1,2)
Authors: MATHUR, P
MANIMARAN, B
TRIVEDI, R
HOSSAIN, MM
ARABATTI, M
Keywords: bidentate organosulfur ligands
acetylenic bond reduction
crystal-structure
methylene groups
metal-complexes
cluster
chemistry
te
se
fe2(co)6(mu-se2)
Issue Date: 1996
Publisher: ELSEVIER SCIENCE SA LAUSANNE
Citation: JOURNAL OF ORGANOMETALLIC CHEMISTRY, 515(1-2), 155-162
Abstract: From the room temperature reaction of (CO)(9)Fe-3(mu(3)-Se)(2) or (CO)(6)Fe-2(mu-Se-2) with diazomethane, four products were isolated; {(CO)(3)Fe(mu-CH2)Se}(2) (1), (CO)(6)Fe-2(mu-SeCH3)(2) (2), (CO)(6)Fe-2(mu-SeCH2Se) (3) and (CO)(6)Fe-2(mu-SeCH2CH2Se) (4). All four 77 compounds were characterised by IR, H-1, C-13, and Se-77 NMR spectroscopy. Structures of 1, 3 and 4 were established by single crystal X-ray structure analyses.
URI: http://dx.doi.org/10.1016/0022-328X(95)06056-3
http://dspace.library.iitb.ac.in/xmlui/handle/10054/7764
http://hdl.handle.net/10054/7764
ISSN: 0022-328X
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