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Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/jspui/handle/10054/7703

Title: Propargyl alcohol derivatives of Fe-2(CO)(6)(mu-EE')(E,E'=S,Se or Te): Synthesis and spectroscopic characterization of (CO)(6)Fe-2{mu-EC(H)=C(CH2OH)E'}(E=Se or Te; E'=S, Se or Te); Crystal structure of (CO)(5)(PPh(3))Fe-2{mu-SeC(CH2OH)=C(H)Se}
Authors: MATHUR, P
HOSSAIN, MM
UMBARKAR, S
SATYANARAYANA, CVV
PURANIK, VG
Keywords: (propargyl)dicobalt hexacarbonyl cations
chalcogen carbonyl-compounds
stabilized carbenium ions
complexes
Issue Date: 1996
Publisher: ELSEVIER SCIENCE SA LAUSANNE
Citation: JOURNAL OF ORGANOMETALLIC CHEMISTRY, 506(1-2), 313-319
Abstract: The propargyl alcohol derivatives (CO)(6)Fe-2{mu-EC(H)=C(CH2OH)E'} (E = Se or Te; E' = S, Se or Te) were obtained from the room-temperature reaction of Fe-2(CO)(6)(mu-EE') with propargyl alcohol and were characterized by IR and H-1, C-13, Se-77 and Te-125 NMR spectroscopy. The structure of the PPh(3)-substituted derivative (CO)(5)(PPh(3))Fe-2{mu-SeC(CH2OH)=C(H)Se} was established by a single crystal X-ray diffraction study.
URI: http://dx.doi.org/10.1016/0022-328X(95)05750-J
http://dspace.library.iitb.ac.in/xmlui/handle/10054/7703
http://hdl.handle.net/10054/7703
ISSN: 0022-328X
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