Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/xmlui/handle/10054/7669
Title: MIXED CHALCOGEN CARBONYL-COMPOUNDS - SYNTHESIS AND CHARACTERIZATION OF (CO)6FE2(MU-3-SE)(MU-3-TE)PT(PPH3)2 AND FE3(CO)7(PPH3)2(MU-3-SE)(MU-3-TE)
Authors: MATHUR, P
CHAKRABARTY, D
HOSSAIN, MM
Keywords: Cluster Compounds
Reactivity
Chemistry
Complexes
Issue Date: 1991
Publisher: ELSEVIER SCIENCE SA LAUSANNE
Citation: JOURNAL OF ORGANOMETALLIC CHEMISTRY, 401(1-2), 167-172
Abstract: An improved method for the isolation of pure Fe3(CO)9(mu-3-Se)(mu-3-Te) and Fe2(CO)6(mu-SeTe) has been developed. The mixed metal mixed chalcogenide complex (CO)6Fe2(mu-3-Se)(mu-3-Te)Pt(PPh3)2 is formed exclusively on treatment of Fe2(CO)6(mu-3-Se)(mu-3-Te) with Pt(C2H4)(PPh3)2, or along with Fe3(CO)7(PPh3)2(mu-3-Se)(mu-3-Te) when Fe3(CO)9(mu-3-Se)(mu-3-Te) is treated with Pt(PPh3)4. With PPh3, Fe3(CO)9(mu-3-Se)(mu-3-Te) forms an adduct, (CO)6Fe2(mu-3-Se)(mu-3-Te)Fe(CO)3PPh3.
URI: http://dx.doi.org/10.1016/0022-328X(91)86204-4
http://dspace.library.iitb.ac.in/xmlui/handle/10054/7669
http://hdl.handle.net/10054/7669
ISSN: 0022-328X
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