INSERTION OF METHYLENE GROUP INTO FE-TE BOND - SYNTHESIS AND CHARACTERIZATION OF ((CO)(3)FE(MU-CH2)TE)(2)

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Title:	INSERTION OF METHYLENE GROUP INTO FE-TE BOND - SYNTHESIS AND CHARACTERIZATION OF ((CO)(3)FE(MU-CH2)TE)(2)
Authors:	MATHUR, P MANIMARAN, B HOSSAIN, MM SATYANARAYANA, CVV PURANIK, VG TAVALE, SS
Keywords:	bidentate organosulfur ligands chalcogen carbonyl-compounds structural characterization cluster compounds reactivity reduction chemistry complex fe3(mu-3-te)2(co)9 fe2(co)6(mu-se2)
Issue Date:	1995
Publisher:	ELSEVIER SCIENCE SA LAUSANNE
Citation:	JOURNAL OF ORGANOMETALLIC CHEMISTRY, 493(1-2), 251-255
Abstract:	A novel methylene insertion product is reported. The new compound {(CO)(3)Fe(mu-CH2)Te}(2) has been isolated from the reaction of the mixed-chalcogenide compound Fe-2(CO)(6)(mu-STe) with diazomethane. It has been characterized by IR, H-1, C-13 and Te-125 NMR spectroscopy. Its structure has been determined by single-crystal X-ray diffraction methods: monoclinic; space group, P2(1)/c; a = 6.743(2), b = 10.996(2), c = 18.007(2) Angstrom, beta = 96.60(2)degrees; V = 1326.3(2) Angstrom(3); Z = 4; F(000) = 1024; Mo K alpha radiation (graphite monochromated); mu = 6.53 mm(-1); T = 293 K; D-c = 2.86 g cm(-3); R = 0.065 (R(w) = 0.064).
URI:	http://dx.doi.org/10.1016/0022-328X(94)05353-D http://dspace.library.iitb.ac.in/xmlui/handle/10054/7651 http://hdl.handle.net/10054/7651
ISSN:	0022-328X
Appears in Collections:	Article

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