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Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/jspui/handle/10054/7593

Title: Diacetylene-bridged clusters: Synthesis and Characterization of (CO)(6)Fe2Se2{mu-HC=C(C equivalent to CR)}, {(CO)(6)Fe2Se2}(2){mu-HC-C(C equivalent to CR)}(R=Me on n-Bu) and (CO)(6)Fe2Se2(mu-HC=CC-CCH3)Os-3(CO)(10)
Authors: MATHUR, P
HOSSAIN, MM
RHEINGOLD, AL
Keywords: acetylenic bond reduction
molecular-structure
coordination chemistry
triosmium clusters
crystal-structure
complex
fe2(co)6(mu-se2)
diynes
os3(co)11(ncme)
reactivity
Issue Date: 1996
Publisher: ELSEVIER SCIENCE SA LAUSANNE
Citation: JOURNAL OF ORGANOMETALLIC CHEMISTRY, 507(1-2), 187-195
Abstract: The compounds (CO)(6)Fe2Se2(mu-HC=C(C=CR)) (R=Me (1) or n-Bu (2)) and ((CO)(6)Fe2Se2)(2)(mu-HC-C(C=CR)} (R=Me (3) or n-Bu (4)) have been obtained by room-temperature reactions of Fe-2(CO)(6)(mu-Se-2) with HC=CC=CR. Compound 1 reacts with Os-3(CO)(10)(NCMe)(2) to give (CO)(6)Fe2Se2(mu-HC=CC-CCH3)Os-3(CO)(10) (5). The structure of compounds 1, 3 and 5 have been established by single-crystal X-ray diffraction studies.
URI: http://dx.doi.org/10.1016/0022-328X(95)05727-7
http://dspace.library.iitb.ac.in/xmlui/handle/10054/7593
http://hdl.handle.net/10054/7593
ISSN: 0022-328X
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