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Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/jspui/handle/10054/7563

Title: ADDITION OF METHYLENE GROUPS TO FE3(CO)9(MU-3-TE)2
Authors: MATHUR, P
REDDY, VD
BOHRA, R
Keywords: polynuclear metal-complexes
x-ray structure
crystal-structures
molecular-structure
bridging carbene
carbyne ligands
multiple bonds
mu-methylene
chemistry
iron
Issue Date: 1991
Publisher: ELSEVIER SCIENCE SA LAUSANNE
Citation: JOURNAL OF ORGANOMETALLIC CHEMISTRY, 401(3), 339-346
Abstract: At room temperature, Fe3(CO)9(mu-Te)2 reacts with diazomethane to form (CO)6Fe2(mu-TeCH2Te) (I) and (CO)6Fe2Te2(CH2)2 (II). Complexes I and II have been separated by chromatography and characterised by IR and NMR spectroscopy, mass spectrometry and microanalysis. Complex I was also subjected to an X-ray diffraction study. The crystals are monoclinic, space group P2(1)/c with a = 6.864(2), b = 13.926(3), c = 14.159(3) angstrom, beta = 104.43(2)-degrees, V = 1310.6(5) angstrom, Z = 4, D(c) = 2.79 g cm-3 and R = 0.043.
URI: http://dx.doi.org/10.1016/0022-328X(91)86230-N
http://dspace.library.iitb.ac.in/xmlui/handle/10054/7563
http://hdl.handle.net/10054/7563
ISSN: 0022-328X
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