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Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/jspui/handle/10054/7562

Title: ACETYLENIC DERIVATIVES OF FE-2(CO)(6)(MU-SE-2) - SYNTHESIS AND SPECTROSCOPIC CHARACTERIZATION OF [(CO)(6)FE-2(MU-SEC(H)=C(H)SE)] AND [((CO)(6)FE2SE2)(2)(MU-C(H)-C(H))]
Authors: MATHUR, P
DASH, AK
HOSSAIN, MM
SATYANARAYANA, CVV
Keywords: bond reduction
clusters
complexes
ligands
fe2(co)6(mu-se2)
se
te
Issue Date: 1995
Publisher: ELSEVIER SCIENCE SA LAUSANNE
Citation: JOURNAL OF ORGANOMETALLIC CHEMISTRY, 493(1-2), 257-260
Abstract: The new acetylenic derivatives [(CO)(6)Fe-2{mu-SeC(H)=C(H)Se}] and [{(CO)(6)Fe2Se2}(2){mu-C(H)-C(H)}] have been isolated from the room-temperature reaction of Fe-2(CO)(6)(mu-Se-2) with acetylene in methanol solvent containing sodium acetate. The products have been characterized by IR and H-1, C-13 and Se-77 NMR spectroscopy. The NMR spectroscopic features of the related phenylacetylene derivatives[(CO)(6)Fe-2{mu-SeC(Ph)=C(H)Se}] and [{(CO)(6)Fe2Se2}(2){mu-C(Ph)-C(H)}] are also reported.
URI: http://dx.doi.org/10.1016/0022-328X(94)05350-K
http://dspace.library.iitb.ac.in/xmlui/handle/10054/7562
http://hdl.handle.net/10054/7562
ISSN: 0022-328X
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