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Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/jspui/handle/10054/7508

Title: Synthesis and characterization of a novel chiral azomethine diselenide
Authors: PANDA, S
ZADE, SS
SINGH, HB
WOLMERSHAUSER, G
Keywords: center-dot-n
selenium electrophiles
asymmetric methoxyselenenylation
structural-characterization
organoselenium compounds
nonbonded interactions
organochalcogen se
te compounds
alkenes
reactivity
Issue Date: 2005
Publisher: ELSEVIER SCIENCE SA
Citation: JOURNAL OF ORGANOMETALLIC CHEMISTRY, 690(13), 3142-3148
Abstract: The first chiral diselenide 9 having an ortho-azomethine functional group has been synthesized by the reaction of bis(o-formylphenyl) diselenide with the chiral amine R(+)-(1-phenylethylamine). The chiral diselenide 9 was further characterized by derivatizing it into the corresponding selenenyl halides. The derivatives are characterized by single crystal X-ray diffraction studies. In the solid state, the bromide derivative 11 shows the strongest (SeN)-N-... intramolecular interaction. The chiral azomethine diselenide 9 has been further reduced to afford the diselenide 13. The monoselenide analogues of 9 and 13 have also been synthesized. (c) 2005
URI: http://dx.doi.org/10.1016/j.jorganchem.2005.04.005
http://dspace.library.iitb.ac.in/xmlui/handle/10054/7508
http://hdl.handle.net/10054/7508
ISSN: 0022-328X
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