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|Title:||Synthesis and characterization of a novel chiral azomethine diselenide|
|Publisher:||ELSEVIER SCIENCE SA|
|Citation:||JOURNAL OF ORGANOMETALLIC CHEMISTRY, 690(13), 3142-3148|
|Abstract:||The first chiral diselenide 9 having an ortho-azomethine functional group has been synthesized by the reaction of bis(o-formylphenyl) diselenide with the chiral amine R(+)-(1-phenylethylamine). The chiral diselenide 9 was further characterized by derivatizing it into the corresponding selenenyl halides. The derivatives are characterized by single crystal X-ray diffraction studies. In the solid state, the bromide derivative 11 shows the strongest (SeN)-N-... intramolecular interaction. The chiral azomethine diselenide 9 has been further reduced to afford the diselenide 13. The monoselenide analogues of 9 and 13 have also been synthesized. (c) 2005|
|Appears in Collections:||Article|
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