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| Title: | Ruthenium(II) chemistry of phosphorus-based ligands, Ph2PN(R)PPh2 (R = Me or Ph) and Ph2PN(Ph)P(E) Ph-2 (E = S or Se). Solution thermochemical study of ligand substitution reactions in the Cp ' RuCl(COD) (Cp ' = Cp, Cp*; COD = cyclooctadiene) system |
| Authors: | BALAKRISHNA, MS
PANDA, R
SMITH, DC
KLAMAN, A
NOLAN, SP |
| Keywords: | tertiary phosphine-ligands
bond disruption enthalpies
transition-metal chemistry
f-element thermochemistry
organoruthenium thermochemistry
molecular-structure
bidentate ligands
complexes
hydrogen
energies |
| Issue Date: | 2000 |
| Publisher: | ELSEVIER SCIENCE SA |
| Citation: | JOURNAL OF ORGANOMETALLIC CHEMISTRY, 599(2), 159-165 |
| Abstract: | The enthalpies of reactions of Cp'RuCl(COD) (Cp' = Cp, Cp*; COD = cyclooctadiene) with bis(phosphino)amines of the type Ph2PN(R)PPh2(R =Me 1 or R = Ph 2) and the monochalcogen derivatives Ph2PN(Ph)P(E)Ph-2(E = S 3 or Se 4) leading to the formation of Cp'RuCl(PNP) and Cp'RuCl{PNP(E)} complexes, respectively, have been measured by anaerobic solution calorimetry in THF at 30 degrees C. These reactions are clean and quantitative. The synthesis and characterization of new organoruthenium complexes is reported. Comparisons with enthalpy data in this two related organoruthenium systems and other similar organometallic systems are also presented. (C) 2000 Elsevier Science S.A. . |
| URI: | http://dx.doi.org/10.1016/S0022-328X(99)00758-5
http://dspace.library.iitb.ac.in/xmlui/handle/10054/7471
http://hdl.handle.net/10054/7471 |
| ISSN: | 0022-328X |
| Appears in Collections: | Article
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