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Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/jspui/handle/10054/7410

Title: Mixed-ligand silver(I) complexes containing bis[2-(diphenylphosphino)phenyl]ether and pyridyl ligands
Authors: BALAKRISHNA, MS
VENKATESWARAN, R
MOBIN, SM
Keywords: transition-metal chemistry
cross-coupling reactions
bite angle
diphosphine ligands
ruthenium(ii) complexes
molecular-structures
ru(ii) complexes
palladium
hydrogenation
crystal
Issue Date: 2009
Publisher: ELSEVIER SCIENCE SA
Citation: INORGANICA CHIMICA ACTA, 362(1), 271-276
Abstract: The reaction of [Ag(2)(k(2)-P,P'-DPEphos)(2)(mu-OTf)(2)] (1) (DPEphos = bis(2-(diphenylphosphino)phenyl]ether) with 1,10-phenanthroline (phen) and 4,4'-bipyridine in equimolar ratios afford, respectively, the mononuclear complex [Ag(k(2)-P,P'-DPEphos)(phen)][OTf] (2) and the coordination polymer [Ag(k(2)-P,P'-DPEphos)(mu-4,4'-bpy)](n)[OTf](n) (3). In complex 3, the silver atoms are bridged by 4,4'-bipyridine units to form a zigzag metallopolymer. (c) 2008
URI: http://dx.doi.org/10.1016/j.ica.2008.02.037
http://dspace.library.iitb.ac.in/xmlui/handle/10054/7410
http://hdl.handle.net/10054/7410
ISSN: 0020-1693
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