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Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/jspui/handle/10054/7401

Title: Mercury chalcogenolates of a ligand having both sterically more bulkier and intramolecularly coordinating features: first isolation of a novel air stable mercury tellurolate
Authors: KANDASAMY, K
SINGH, HB
WOLMERSHAUSER, G
Keywords: monomeric selenolato complexes
center-dot-n
structural-characterization
molecular-structures
crystal-structures
zinc
cadmium
derivatives
precursors
chemistry
Issue Date: 2005
Publisher: ELSEVIER SCIENCE SA
Citation: INORGANICA CHIMICA ACTA, 358(1), 207-212
Abstract: Synthesis and characterization of stable monomeric mercury selenolate (9) and the novel air stable mercury tellurolate (10) incorporating [2-[1-(3,5 dimethylphenyl)-2-naphthyl]-4,5-dihydro-4,4-dimethyloxazole], containing both sterically more demanding and intramolecularly coordinating groups have been described here. These complexes were prepared in good yields by oxidative addition of mercury metal to the corresponding dichalcogenides in methanol. FT-IR, multinuclear (H-1, C-13, Se-77 and Te-125) NMR, thermal analysis and mass spectrometric techniques were used to characterize these complexes. The complex 9 was structurally characterized by single-crystal X-ray diffraction analysis. (C) 2004
URI: http://dx.doi.org/10.1016/j.ica.2004.08.020
http://dspace.library.iitb.ac.in/xmlui/handle/10054/7401
http://hdl.handle.net/10054/7401
ISSN: 0020-1693
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