First organotin complex of a phosphonic diamide RP(O)(NHR)(2)

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Title:	First organotin complex of a phosphonic diamide RP(O)(NHR)(2)
Authors:	MURUGAVEL, R POTHIRAJA, R SHANMUGAN, S SINGH, N BUTCHER, RJ
Keywords:	lewis base activation ray crystal-structure enantioselective allylation mossbauer-spectra adducts oxide stoichiometry diphosphine phosphine aldehydes
Issue Date:	2007
Publisher:	ELSEVIER SCIENCE SA
Citation:	JOURNAL OF ORGANOMETALLIC CHEMISTRY, 692(10), 1920-1923
Abstract:	Diorganotin dichloride-phosphonic diamide complex, [Ph2SnCl2(tBuP(O)((NHPr)-Pr-i)(2))(2)] (1), is prepared by the addition of two equivalents of (BuP)-Bu-t(O)((NHPr)-Pr-i)(2) to one equivalents of Ph2SnCl2 either in the presence or absence of triethylamine. Compound 1 is a rare example of an all-trans SnA(2)B(2)C(2) complex that contains H-bonded six-membered rings which are made up of six different main group elements. (c) 2007
URI:	http://dx.doi.org/10.1016/j.jorganchem.2006.12.044 http://dspace.library.iitb.ac.in/xmlui/handle/10054/7343 http://hdl.handle.net/10054/7343
ISSN:	0022-328X
Appears in Collections:	Article

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