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Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/jspui/handle/10054/7343

Title: First organotin complex of a phosphonic diamide RP(O)(NHR)(2)
Authors: MURUGAVEL, R
POTHIRAJA, R
SHANMUGAN, S
SINGH, N
BUTCHER, RJ
Keywords: lewis base activation
ray crystal-structure
enantioselective allylation
mossbauer-spectra
adducts
oxide
stoichiometry
diphosphine
phosphine
aldehydes
Issue Date: 2007
Publisher: ELSEVIER SCIENCE SA
Citation: JOURNAL OF ORGANOMETALLIC CHEMISTRY, 692(10), 1920-1923
Abstract: Diorganotin dichloride-phosphonic diamide complex, [Ph2SnCl2(tBuP(O)((NHPr)-Pr-i)(2))(2)] (1), is prepared by the addition of two equivalents of (BuP)-Bu-t(O)((NHPr)-Pr-i)(2) to one equivalents of Ph2SnCl2 either in the presence or absence of triethylamine. Compound 1 is a rare example of an all-trans SnA(2)B(2)C(2) complex that contains H-bonded six-membered rings which are made up of six different main group elements. (c) 2007
URI: http://dx.doi.org/10.1016/j.jorganchem.2006.12.044
http://dspace.library.iitb.ac.in/xmlui/handle/10054/7343
http://hdl.handle.net/10054/7343
ISSN: 0022-328X
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