Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/xmlui/handle/10054/7342
Title: Fe(CO)(5) promoted C-S bond activation and formation of an unusual C(2)S(3) ligand in [{Fe(2)(CO)(6)}(2)(mu-C(2)S(3))]
Authors: MATHUR, P
BOODIDA, S
JI, RS
MOBIN, SM
Keywords: Crystal-Structures
Carbon-Disulfide
Structural-Characterization
Complexes
Cleavage
Cs2
Cluster
Fe2(Co)6(Mu-Se2)
Elimination
Derivatives
Issue Date: 2009
Publisher: ELSEVIER SCIENCE SA
Citation: JOURNAL OF ORGANOMETALLIC CHEMISTRY, 694(18), 3043-3045
Abstract: Photolysis of a hexane solution containing Fe(CO)(5) and CS(2) leads to desulfurization and formation of a novel cluster [{Fe(2)(CO)(6)}(2)(mu-C(2)S(3))] (1). Its molecular structure was determined by single crystal X-ray diffraction methods and shown to consist of two distinct Fe(2)(CO)(6) units linked by an unusual C(2)S(3) unit. (C) 2009
URI: http://dx.doi.org/10.1016/j.jorganchem.2009.05.023
http://dspace.library.iitb.ac.in/xmlui/handle/10054/7342
http://hdl.handle.net/10054/7342
ISSN: 0022-328X
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