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Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/jspui/handle/10054/7105

Title: Three-dimensional sodium phosphinates derived from a bis-functionalized phosphinic acid
Authors: MURUGAVEL, R
SHANMUGAN, S
GOGOI, N
Keywords: metal
transformations
cages
rings
Issue Date: 2010
Publisher: ELSEVIER SCIENCE BV
Citation: INORGANIC CHEMISTRY COMMUNICATIONS, 13(12), 1530-1533
Abstract: The synthesis and crystal structures of two three-dimensional sodium phosphinates are reported. While [Na(2) {(CH(2)OH)(2)PO(2)}(2)(H(2)O)](n) (1) is formed from the direct reaction of bis(hydroxylmethyl)phosphinic acid with NaOH, the addition of 1,10-phenanthroline to the above reaction mixture results in the formation of [Na(2) {(CH(2)OH)(2)PO(2)}(2)](n) (2). The basic structural unit of the 3D polymeric networks in both 1 and 2 is a dimeric Na(2)L(2) moiety. In case of 1, these units are interconnected through coordination via phosphoryl and alcoholic oxygen atoms to eventually result in a three-dimensional network. However in the case of 2, only the phosphoryl oxygen is responsible for gluing the Na(2)L(2) dimeric units into a three-dimensional framework. .
URI: http://dx.doi.org/10.1016/j.inoche.2010.09.004
http://dspace.library.iitb.ac.in/xmlui/handle/10054/7105
http://hdl.handle.net/10054/7105
ISSN: 1387-7003
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