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Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/jspui/handle/10054/6924

Title: RELATIVE REDUCING ABILITIES IN-VITRO OF SOME HYDROXY-CONTAINING COMPOUNDS, INCLUDING MONOSACCHARIDES, TOWARDS VANADIUM(V) AND MOLYBDENUM(VI)
Authors: BANDWAR, RP
RAO, CP
Keywords: perchloric-acid medium
d-glucose
oxidation
kinetics
oxyanions
vanadate
tetrachloroaurate(iii)
hexachloroiridate(iv)
mechanism
Issue Date: 1995
Publisher: ELSEVIER SCIENCE BV
Citation: CARBOHYDRATE RESEARCH, 277(2), 197-207
Abstract: The reduction of vanadium(V) and molybdenum(VI) has been carried out in aqueous HCl by various hydroxy-containing compounds such as hexoses (D-glucose, D-fructose, and D-galactose), pentoses (D-ribose and D-xylose), glycols [ethylene glycol, di(ethylene glycol), tri(ethylene glycol), tetra(ethylene glycol), and poly(ethylene glycol)], and mono-, di-, and tri-ethanolamines. The relative reducing abilities of these compounds are compared with those of L-ascorbic acid and L-cysteine. The trend is similar to that reported earlier for chromium(VI) reduction. Based on this study it is concluded that hydroxy-containing compounds play important roles in complexation and reduction of metal ions.
URI: http://dx.doi.org/10.1016/0008-6215(95)00209-C
http://dspace.library.iitb.ac.in/xmlui/handle/10054/6924
http://hdl.handle.net/10054/6924
ISSN: 0008-6215
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