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Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/jspui/handle/10054/6918

Title: Reductive cleavage of azo dyes and reduction of nitroarenes over trivalent iron incorporated hexagonal mesoporous aluminophosphate molecular sieves
Authors: MOHAPATRA, SK
SONAVANE, SU
JAYARAM, RV
SELVAM, P
Keywords: catalytic transfer hydrogenation
meerwein-ponndorf-verley
oxide hydroxide catalyst
aromatic nitro-compounds
hydrazine hydrate
heterogeneous catalysts
nitroaromatic compounds
oppenauer reactions
carbonyl-compounds
organic-compounds
Issue Date: 2003
Publisher: ELSEVIER SCIENCE BV
Citation: APPLIED CATALYSIS B-ENVIRONMENTAL, 46(1), 155-163
Abstract: A novel, efficient and eco-friendly iron incorporated hexagonal mesoporous aluminiphosphate (FeHMA) catalyst is put forward for the reductive cleavage of azo functions as well as for the reduction of nitroarenes, including larger molecules, by catalytic transfer hydrogenation (CTH). The results indicate that the transformations occur in elegant and rapid manner with excellent yields. Furthermore, the catalyst can easily be recovered and reused without practically affecting the yields for up to six cycles. (C) 2003
URI: http://dx.doi.org/10.1016/S0926-3373(03)00182-6
http://dspace.library.iitb.ac.in/xmlui/handle/10054/6918
http://hdl.handle.net/10054/6918
ISSN: 0926-3373
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