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Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/jspui/handle/10054/6432

Title: CHROMATE REDUCTION - REDUCTION OF POTASSIUM CHROMATE BY D-GLUCOSE AND D-FRUCTOSE TO FORM CR(III)-SACCHARIDE COMPLEXES
Authors: RAO, CP
KAIWAR, SP
Keywords: electron-paramagnetic-res
chromium(vi)
glutathione
mechanism
adducts
cr(vi)
sugar
cr3+
ion
Issue Date: 1992
Publisher: ELSEVIER SCIENCE BV
Citation: CARBOHYDRATE RESEARCH, 237(), 195-202
Abstract: The reduction of chromate by saccharides is of paramount importance in the context of chromium transport in biological and ecological systems. Potassium chromate has been shown to be reduced by D-glucose and D-fructose to form Cr(III)-saccharide complexes via an intermediate Cr(V) species. These saccharide complexes have been isolated in the solid state for the first time and characterized by analytical, spectroscopic, magnetic and electrochemical methods. Bridged dinuclear saccharide complexes of Cr(III) have been proposed.
URI: http://dspace.library.iitb.ac.in/xmlui/handle/10054/6432
http://hdl.handle.net/10054/6432
ISSN: 0008-6215
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