A novel dimeric copper salicylate with an undissociated COOH group: Synthesis and crystal structure of [Cu-2(HSal)(Sal)(2,2 '-bpy)(2)](ClO4)

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Title:	A novel dimeric copper salicylate with an undissociated COOH group: Synthesis and crystal structure of [Cu-2(HSal)(Sal)(2,2 '-bpy)(2)](ClO4)
Authors:	PALANISAMI, N PRABUSANKAR, G MURUGAVEL, R
Keywords:	earth metal-ions coordination polymers complexes acid perchlorate 1,10-phenanthroline architectures dihydrate ligands
Issue Date:	2006
Publisher:	ELSEVIER SCIENCE BV
Citation:	INORGANIC CHEMISTRY COMMUNICATIONS, 9(10), 1002-1006
Abstract:	A dinuclear copper salicylate [Cu-2(HSal)(Sal)(2,2'-bpy)(2)](ClO4) (1) (H(2)Sal = salicylic acid) has been synthesized and characterized with the aid of elemental analysis and infrared, ultraviolet and fluorescence spectroscopic studies. The molecular structure of 1, determined by single-crystal X-ray diffraction studies, shows the presence of incompletely deprotonated salicylate ligands in the complex. Hydrogen bonding interactions and pi-pi aromatic stacking lead to the formation of 2D polymeric structure in the solid state. (C) 2006
URI:	http://dx.doi.org/10.1016/j.inoche.2006.05.025 http://dspace.library.iitb.ac.in/xmlui/handle/10054/6333 http://hdl.handle.net/10054/6333
ISSN:	1387-7003
Appears in Collections:	Article

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