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Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/jspui/handle/10054/6333

Title: A novel dimeric copper salicylate with an undissociated COOH group: Synthesis and crystal structure of [Cu-2(HSal)(Sal)(2,2 '-bpy)(2)](ClO4)
Authors: PALANISAMI, N
PRABUSANKAR, G
MURUGAVEL, R
Keywords: earth metal-ions
coordination polymers
complexes
acid
perchlorate
1,10-phenanthroline
architectures
dihydrate
ligands
Issue Date: 2006
Publisher: ELSEVIER SCIENCE BV
Citation: INORGANIC CHEMISTRY COMMUNICATIONS, 9(10), 1002-1006
Abstract: A dinuclear copper salicylate [Cu-2(HSal)(Sal)(2,2'-bpy)(2)](ClO4) (1) (H(2)Sal = salicylic acid) has been synthesized and characterized with the aid of elemental analysis and infrared, ultraviolet and fluorescence spectroscopic studies. The molecular structure of 1, determined by single-crystal X-ray diffraction studies, shows the presence of incompletely deprotonated salicylate ligands in the complex. Hydrogen bonding interactions and pi-pi aromatic stacking lead to the formation of 2D polymeric structure in the solid state. (C) 2006
URI: http://dx.doi.org/10.1016/j.inoche.2006.05.025
http://dspace.library.iitb.ac.in/xmlui/handle/10054/6333
http://hdl.handle.net/10054/6333
ISSN: 1387-7003
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