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|Title: ||A novel dimeric copper salicylate with an undissociated COOH group: Synthesis and crystal structure of [Cu-2(HSal)(Sal)(2,2 '-bpy)(2)](ClO4)|
|Authors: ||PALANISAMI, N|
|Keywords: ||earth metal-ions|
|Issue Date: ||2006|
|Publisher: ||ELSEVIER SCIENCE BV|
|Citation: ||INORGANIC CHEMISTRY COMMUNICATIONS, 9(10), 1002-1006|
|Abstract: ||A dinuclear copper salicylate [Cu-2(HSal)(Sal)(2,2'-bpy)(2)](ClO4) (1) (H(2)Sal = salicylic acid) has been synthesized and characterized with the aid of elemental analysis and infrared, ultraviolet and fluorescence spectroscopic studies. The molecular structure of 1, determined by single-crystal X-ray diffraction studies, shows the presence of incompletely deprotonated salicylate ligands in the complex. Hydrogen bonding interactions and pi-pi aromatic stacking lead to the formation of 2D polymeric structure in the solid state. (C) 2006|
|Appears in Collections:||Article|
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