DSpace at IIT Bombay >
IITB Publications >
Please use this identifier to cite or link to this item:
|Title: ||Transition-metal saccharide chemistry: Synthesis and characterization of D-glucose, D-fructose, D-galactose, D-xylose, D-ribose, and maltose complexes of Co(II)|
|Authors: ||BANDWAR, RP|
|Issue Date: ||1997|
|Publisher: ||ELSEVIER SCI LTD|
|Citation: ||CARBOHYDRATE RESEARCH, 297(4), 333-339|
|Abstract: ||Monosaccharide (D-Glc, D-Fru, D-Gal, D-Xyl, and D-Rib) and disaccharide (Mall complexes of Co(II) were synthesised from nonaqueous solutions using [NEt(4)](2)[CoCl2Br2] or CoCl2 . 6H(2)O and isolated in the solid state. The purified complexes were characterized by diffuse reflectance, aqueous solution absorbance, CD, FTIR, magnetic susceptibility, EPR, and cyclic voltammetric studies. The complexes synthesised from [NEt(4)](2)[CoCl2Br2] were found to be primarily dinuclear, whereas those synthesised from CoCl2 . 6H(2)O were found to be di- or tetra-nuclear. The hydrolytic stability of the complexes followed a trend: D-Rib > Mal > D-Glc > D-Xyl > D-Fru much greater than D-Gal. (C) 1997 .|
|Appears in Collections:||Article|
Files in This Item:
There are no files associated with this item.
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.