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| Title: | SYNTHESES OF 3-SUBSTITUTED CHIRAL BORNEOLS AND ISOBORNEOLS AND THEIR ACRYLATES - PRECURSORS FOR PI-FACIAL SELECTIVE REACTIONS |
| Authors: | NADKARNI, PJ
SAWANT, MS
TRIVEDI, GK |
| Keywords: | nuclear magnetic-resonance
diels-alder additions
asymmetric induction
substituent |
| Issue Date: | 1995 |
| Publisher: | COUNCIL SCIENTIFIC INDUSTRIAL RESEARCH |
| Citation: | INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY, 34(6), 474-483 |
| Abstract: | A simple synthetic procedure has been described for the syntheses of a few chiral secondary alcohols such as 3-phenylthiomethyl- and 3-phenylsulfonylmethyl-borneols and -isoborneols, potentially useful as chiral auxiliaries. Effect of 3-substitution in these molecules on the proton and carbon resonances has been dehydrochlorination with 1, 8-diazabicyclo[5.4.0]undecene-7 (DBU) has been demonstrated for the formation of acrylates in moderate to very good yields. |
| URI: | http://dspace.library.iitb.ac.in/xmlui/handle/10054/5736
http://hdl.handle.net/10054/5736 |
| ISSN: | 0376-4699 |
| Appears in Collections: | Article
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