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Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/jspui/handle/10054/5516

Title: Conformational studies of sterically comparable 2,4-disubstituted bicyclo[3.3.1]nonan-9-one systems .2.
Authors: RAVISHANKAR, L
KORDE, SS
TRIVEDI, GK
Keywords: acid
Issue Date: 1996
Publisher: COUNCIL SCIENTIFIC INDUSTRIAL RESEARCH
Citation: INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY, 35(1), 1-4
Abstract: Condensation of cyclohexanone with cinnamaldehyde and morpholine in the presence of anhydrous CeCl3 results in the formation of two isomers of 2-morpholino-4-phenylbicyclo[3.3.1]nonan-9-one, besides two other products. The stereochemistry of the minor isomer has been determined with the help of H-1 NMR, COSY, C-13 NMR techniques and H-1 shift reagent studies on sterically comparable 2,4-diphenyl-bicyclo[3.3.1]nonan-9-one. In this case the molecule exists in a twin-chair conformation with the two substituents diequatorially oriented.
URI: http://dspace.library.iitb.ac.in/xmlui/handle/10054/5516
http://hdl.handle.net/10054/5516
ISSN: 0376-4699
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