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Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/jspui/handle/10054/5498

Title: C-13 NMR-SPECTRA OF 2-FUNCTIONALIZED DELTA(4)-3-KETO STEROIDS - CARBON-1 AND CARBON-19 PROBES FOR CONFORMATIONAL PREFERENCE
Authors: DESAI, UR
TRIVEDI, GK
Keywords: nuclear magnetic-resonance
circular-dichroism
medroxyprogesterone acetate
c-13
spectroscopy
19-nortestosterone
binding
hydroxy
Issue Date: 1991
Publisher: COUNCIL SCIENTIFIC INDUSTRIAL RESEARCH
Citation: INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY, 30(10), 915-919
Abstract: The C-13 NMR spectra of 2-substituted 4-en-3-one steroids have been studied. The functional groups include 2-alpha- and 2-beta-substituted 3-thia-butanoate or 4-thia-pentanoate moieties. The analysis mainly reflects on the gamma-interactions of gauche nature and syn-diaxial interactions. A simple protocol for the conformational analyis on ring A of these steroids has been postulated based upon the resonances of carbon-1 and carbon-19.
URI: http://dspace.library.iitb.ac.in/xmlui/handle/10054/5498
http://hdl.handle.net/10054/5498
ISSN: 0376-4699
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