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Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/jspui/handle/10054/5453

Title: Cycloaddition of 6-hydroxy-2,6-dimethylcyclohexa-2,4-dienone: A stereoselective entry into functionalized bicyclo[2.2.2]octanes and a novel 1,2-migration of methyl group
Authors: SINGH, V
CHANDRA, G
MOBIN, SM
Keywords: homoallyl radical rearrangement
1st total-synthesis
enantioselective synthesis
periodate oxidation
route
ring
cyclohexa-2,4-dienones
construction
dimerization
phenols
Issue Date: 2008
Publisher: COUNCIL SCIENTIFIC & INDUSTRIAL RES
Citation: INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY, 47(12), 1886-1891
Abstract: Cycloaddition of 6-hydroxy-2,6-dimethylcyclohexa-2,4-dienones with ethyl vinyl ether, butyl vinyl ether, vinyl acetate and vinyl phenyl sulphone leading to a stereoselective entry into bicyclo[2.2.2]octanes having quaternary methyl group is reported. A novel thermal 1,2-methyl migration has also been described.
URI: http://dspace.library.iitb.ac.in/xmlui/handle/10054/5453
http://hdl.handle.net/10054/5453
ISSN: 0376-4699
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